Can a organization accout (office 365) be used for live/Microsoft services ??

I understand that office 365 is on separate domain and live id (Microsoft account) is used for consumer applications.

But can an office365 account get live/Microsoft services ??

The issue is we trying to SSO office 365 applications and Azure ML (used with Microsoft account) but as the domains are different i am unable to find any proper help or process on the web.

Thanks